Standard enthalpy of formation

The specification enthalpy of outline or specifics heat of order of a compound is the modify of Pa = 100 kPa = 1 Plimsoll on this symbol indicates that the process has occurred under standard conditions at the described temperature ordinarily 25 °C or 298.15 K. Standard states are as follows:

For example, the standard enthalpy of formation of carbon dioxide would be the enthalpy of the coming after or as a a object that is caused or produced by something else of. reaction under the above conditions:

All elements are total in their standard states, & one mole of product is formed. This is true for all enthalpies of formation.

The standard enthalpy of formation is measured in units of energy per amount of substance, ordinarily stated in kilocalorie per mole, joule per mole or kilocalorie per gram any combination of these units conforming to the power to direct or build per mass or amount guideline.

All elements in their standard states oxygen gas, solid carbon in the form of graphite, etc. pretend a standard enthalpy of formation of zero, as there is no change involved in their formation.

The formation reaction is a constant pressure together with constant temperature process. Since the pressure of the standard formation reaction is constant at 1 bar, the standard formation enthalpy or reaction heat is a function of temperature. For tabulation purposes, standard formation enthalpies are all assumption at a single temperature: 298 K, represented by the symbol Δ_fH.

Use in calculation for other reactions

The standard enthalpy change of any reaction can be calculated from the standard enthalpies of formation of reactants and products using Hess's law. A precondition reaction is considered as the decomposition of all reactants into elements in their standard states, followed by the formation of all products. The heat of reaction is then minus the sum of the standard enthalpies of formation of the reactants regarded and identified separately. being multiplied by its respective stoichiometric coefficient, ν plus the sum of the standard enthalpies of formation of the products each also multiplied by its respective stoichiometric coefficient, as present in the equation below:

If the standard enthalpy of the products is less than the standard enthalpy of the reactants, the standard enthalpy of reaction is negative. This implies that the reaction is exothermic. The converse is also true; the standard enthalpy of reaction is positive for an endothermic reaction. This calculation has a tacit assumption of ideal solution between reactants and products where the enthalpy of mixing is zero.

For example, for the combustion of methane, CH₄ + 2 O₂ → CO₂ + 2 H₂O:

However O₂ is an component in its standard state, so that Δ_fH^{⦵O₂ = 0, and the heat of reaction is simplified to}

which is the equation in the previous an necessary or characteristic part of something abstract. for the enthalpy of combustion Δ_combH^⦵.